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http://repositsc.nuczu.edu.ua/handle/123456789/25347
Повний запис метаданих
Поле DC | Значення | Мова |
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dc.contributor.author | Трегубов, Д.Г. | - |
dc.contributor.author | Слепужніков, Є.Д. | - |
dc.contributor.author | Чиркіна-Харламова, М.А. | - |
dc.contributor.author | Майборода, А.О. | - |
dc.date.accessioned | 2025-07-10T17:27:57Z | - |
dc.date.available | 2025-07-10T17:27:57Z | - |
dc.date.issued | 2025 | - |
dc.identifier.citation | D. Tregubov, Y. Slepuzhnikov, M. Chyrkina-Kharlamovа and A. Maiboroda. Cluster Mechanism of the Explosive Processes Initiation in the Matter. Fire Performance of Materials and Structures.Aggregated Book, №42. Chapter 4: Combustion Modelling. Swetzerlend: Trans Tech Publications, 2025. Р. 145-156. | uk_UA |
dc.identifier.isbn | 978-3-0364-0769-2 | - |
dc.identifier.uri | http://repositsc.nuczu.edu.ua/handle/123456789/25347 | - |
dc.description.abstract | The relationship between substance characteristic temperatures: autoignition, melting, flash, boiling is demonstrated and analyzed. Based on the oscillatory and step changes presence, a conclusion was made about the supramolecular structures presence and periodicity in the n-alkanes homologous series. A method for modeling equivalent lengths of peroxide supramolecular structures for predicting the explosion and fire hazard parameters of n-alkanes is proposed. An approximation dependence was developed for predicting autoignition temperatures tai of n-alkanes. It is shown that stoichiometric concentrations of the various supramolecular peroxide structures formation accord to different flammability and explosion limits. A correlation between tai and Anti-Knock Index (AKI) was established. An approximation dependence was developed for predicting n-alkanes AKI. The detonation propensity index КD was introduced based on cluster supramolecular structures modeling and melting temperatures. It is shown that КD indicator correlates with the n-alkanes AKI and the explosives detonation velocity. The possibility of taking into account during calculations the supramolecular structures presence at the combustion stage confirms their existence. | uk_UA |
dc.language.iso | en | uk_UA |
dc.publisher | Trans Tech Publications | uk_UA |
dc.subject | explosion hazard | uk_UA |
dc.subject | peroxide structures | uk_UA |
dc.subject | cluster | uk_UA |
dc.subject | n-alkanes | uk_UA |
dc.subject | oscillation | uk_UA |
dc.subject | detonation | uk_UA |
dc.subject | autoignition | uk_UA |
dc.subject | characteristic temperature | uk_UA |
dc.title | Cluster Mechanism of the Explosive Processes Initiation in the Matter | uk_UA |
dc.type | Book chapter | uk_UA |
Розташовується у зібраннях: | Кафедра спеціальної хімії та хімічної технології |
Файли цього матеріалу:
Файл | Опис | Розмір | Формат | |
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МоногрTrans.pdf | Модель кластерів горіння | 2,47 MB | Adobe PDF | Переглянути/Відкрити |
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